Making a Living (1914)
Making a Living (also known as Doing His Best, A Busted Johnny, Troubles and Take My Picture) is the first film starring Charlie Chaplin. It premiered on February 2, 1914. Chaplin plays Edgar English, a lady-charming swindler who runs afoul of the Keystone Kops. It was written and directed by Henry Lehrman.
More at Wikipedia.